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The application of regenerable sorbents for mercury capture in gas phase

机译:可再生吸附剂在气相捕集汞中的应用

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摘要

Mercury is a well-known toxic element, and flue gas streams emitted from coal-fired utilities are one of the largest anthropogenic sources of this element. This study briefly reviews the proposed technologies for reducing mercury emissions from coal combustion, focusing on an emerging process which involves the use of regenerable sorbents and especially those loaded with noble metals. Among the mercury species formed during coal combustion, elemental mercury is the most difficult to remove from the flue gases due to its low reactivity and insolubility in water. The widespread interest in using regenerable sorbents with metals is due to their ability to retain elemental mercury. With this technology, not only can efficiencies of 100 % be reached in the retention of elemental mercury but also a way to avoid the generation of new wastes loaded with mercury. This study considers the main aspects that must be taken into account when developing effective regenerable sorbents for mercury capture, with special attention to sorbents containing noble metals. The characteristics of this process are compared with those of other processes in a more advanced state of development.
机译:汞是一种众所周知的有毒元素,燃煤电厂排放的烟道气是该元素的最大人为来源之一。这项研究简要回顾了减少煤炭燃烧产生的汞排放的拟议技术,重点研究了一种新兴工艺,该工艺涉及使用可再生吸附剂,尤其是那些负载有贵金属的吸附剂。在煤燃烧过程中形成的汞物种中,元素汞由于其低反应性和在水中的不溶性而最难以从烟道气中去除。与金属一起使用可再生吸附剂的广泛兴趣是由于它们保留元素汞的能力。使用这项技术,不仅可以达到100%的元素汞保留效率,而且还可以避免产生新的汞废物。这项研究考虑了开发有效的可再生吸附剂用于汞捕集时必须考虑的主要方面,尤其要注意含贵金属的吸附剂。在更高级的开发状态下,将该过程的特征与其他过程的特征进行比较。

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